Extraction and Purification of Various Natural Dyes for the Optimization of Solar Cell Performance
Keywords:
Lawsoniainermis, Baphianitida, Anatase, IndigoferatinctoriaAbstract
Dye-sensitized solar cells (DSSCs) have been the subject of much research and growing attention in recent decades due to their comparably easy fabrication, low toxicity, easy preparation, and relatively low cost. The extraction, purification, and characterization of dyes from various plant sources for use for solar cell applications are investigated in this work. The dyes were applied on a TiO2 layer using a straightforward drop-casting approach. The anatase crystallite structure with a mesoporous shape was successfully deposited, as demonstrated by structural investigations utilizing XRD on the TiO2 layer. According to Electrochemical Impedance Spectroscopy (EIS) investigations, pure cells had the longest electron lifetime and the lowest recombination resistance, which is responsible for the continuous electron transfer across the oxide layer over a greater distance and the improvement of the power conversion efficiency (PCE). I-V characterizations were used to estimate the photovoltaic parameters and the efficiencies of the devices, the overall best performance of η ~ 1.74 % was obtained from the cell fabricated with Lawsoniainermis dye extract.
References
[1] E. Klugmann-Radziemska, P. Ostrowski, K. Drabczyk, P. Panek, and M. Szkodo, “Experimental validation of crystalline silicon solar cells recycling by thermal and chemical methods,” Sol. Energy Mater. Sol. Cells, vol. 94, no. 12, pp. 2275–2282, 2010, doi: 10.1016/j.solmat.2010.07.025.
[2] P. Sinha, “Potential environmental hazards of photovoltaic panel disposal: Discussion of Tammaro et al. (2015),” J. Hazard. Mater., vol. 323, pp. 733–734, 2017, doi: 10.1016/j.jhazmat.2016.04.021.
[3] R. L. Vekariya, K. K. Sonigara, K. B. Fadadu, J. V. Vaghasiya, and S. S. Soni, “Humic Acid as a Sensitizer in Highly Stable Dye Solar Cells: Energy from an Abundant Natural Polymer Soil Component,” ACS Omega, vol. 1, no. 1, pp. 14–18, 2016, doi: 10.1021/acsomega.6b00010.
[4] M. Green, E. Dunlop, J. Hohl-Ebinger, M. Yoshita, N. Kopidakis, and X. Hao, “Solar cell efficiency tables (version 57),” Prog. Photovoltaics Res. Appl., vol. 29, no. 1, pp. 3–15, 2021, doi: 10.1002/pip.3371.
[5] C. P. Lee, C. T. Li, and K. C. Ho, “Use of organic materials in dye-sensitized solar cells,” Mater. Today, vol. 20, no. 5, pp. 267–283, 2017, doi: 10.1016/j.mattod.2017.01.012.
[6] Q. Dai and J. Rabani, “Unusually efficient photosensitization of nanocrystalline TiO2 films by pomegranate pigments in aqueous medium,” New J. Chem., vol. 26, no. 4, pp. 421–426, 2002, doi: 10.1039/b108390b.
[7] H. K. Lee, “Talk Louder So I Can See You,” Neuron, vol. 89, no. 5, pp. 887–888, 2016, doi: 10.1016/j.neuron.2016.02.026.
[8] K. Sharma, V. Sharma, and S. S. Sharma, “Dye-Sensitized Solar Cells: Fundamentals and Current Status,” Nanoscale Res. Lett., vol. 13, 2018, doi: 10.1186/s11671-018-2760-6.
[9] J. Low, B. Cheng, and J. Yu, “Surface modification and enhanced photocatalytic CO 2 reduction performance of TiO 2 : a review,” Appl. Surf. Sci., vol. 392, pp. 658–686, 2017, doi: 10.1016/j.apsusc.2016.09.093.
[10] M. Babudurai et al., “Mechanical activation of TiO2/Fe2O3 nanocomposite for arsenic adsorption: effect of ball-to-powder ratio and milling time,” J. Nanostructure Chem., vol. 11, no. 4, pp. 619–632, 2021, doi: 10.1007/s40097-021-00388-8.
[11] M. Irimia-Vladu, “‘Green’ electronics: Biodegradable and biocompatible materials and devices for sustainable future,” Chem. Soc. Rev., vol. 43, no. 2, pp. 588–610, 2014, doi: 10.1039/c3cs60235d.
[12] B. Sun, G. Zhou, T. Gao, H. Zhang, and H. Yu, “NiO nanosheet/TiO 2 nanorod-constructed p-n heterostructures for improved photocatalytic activity,” Appl. Surf. Sci., vol. 364, pp. 322–331, 2016, doi: 10.1016/j.apsusc.2015.12.158.
[13] Y. Zhao et al., “Fabrication of BiOBr nanosheets@TiO 2 nanobelts p-n junction photocatalysts for enhanced visible-light activity,” Appl. Surf. Sci., vol. 365, pp. 209–217, 2016, doi: 10.1016/j.apsusc.2015.12.249.
[14] Baig, M. M. (2021). Solar cells and its applications. International Journal of All Research Education and Scientific Methods, 7, 3493-3500
[15] H. Kusama, H. Orita, and H. Sugihara, “TiO2 band shift by nitrogen-containing heterocycles in dye-sensitized solar cells: A periodic density functional theory study,” Langmuir, vol. 24, no. 8, pp. 4411–4419, 2008, doi: 10.1021/la703696f.
[16] E. O. Onah et al., “Comparative photo-response performances of dye sensitized solar cells using dyes from selected plants,” Surfaces and Interfaces, vol. 20, no. August, 2020, doi: 10.1016/j.surfin.2020.100619.
[17] A. F. Nogueira, C. Longo, and M. A. De Paoli, “Polymers in dye sensitized solar cells: Overview and perspectives,” Coord. Chem. Rev., vol. 248, no. 13–14, pp. 1455–1468, 2004, doi: 10.1016/j.ccr.2004.05.018.
[18] Z. He, J. Li, D. Wang, J. Wang, and T. Zhang, “Enhanced photovoltaic performance of TiO2 dye-sensitized solar cell based on one-dimensional composite photoanode,” Int. J. Electrochem. Sci., vol. 12, no. 10, pp. 8918–8928, 2017, doi: 10.20964/2017.10.02.
[19] X. Deng, Z. Huang, W. Wang, and R. N. Davé, “Investigation of nanoparticle agglomerates properties using Monte Carlo simulations,” Adv. Powder Technol., vol. 27, no. 5, pp. 1971–1979, 2016, doi: 10.1016/j.apt.2016.06.029.
[20] A. Machrouhi et al., “Effectiveness of beetroot seeds and H3PO4 activated beetroot seeds for the removal of dyes from aqueous solutions,” J. Water Reuse Desalin., vol. 8, no. 4, pp. 522–531, 2018, doi: 10.2166/wrd.2017.034.
[21] W. Li and T. Zeng, “Preparation of TiO2 anatase nanocrystals by TiCl4 hydrolysis with additive H2SO4,” PLoS One, vol. 6, no. 6, pp. 2–7, 2011, doi: 10.1371/journal.pone.0021082.
[22] O. Adedokun, Y. K. Sanusi, and A. O. Awodugba, “Solvent dependent natural dye extraction and its sensitization effect for dye sensitized solar cells,” Optik (Stuttg)., vol. 174, pp. 497–507, 2018, doi: 10.1016/j.ijleo.2018.06.064.
[23] M. K. Hossain et al., “Effect of dye extracting solvents and sensitization time on photovoltaic performance of natural dye sensitized solar cells,” Results Phys., vol. 7, pp. 1516–1523, 2017, doi: 10.1016/j.rinp.2017.04.011.
[24] Z. Xu, Y. Li, and Z. Liu, “Boron, nitrogen, and nickel impurities in GeC nanoribbons: A first-principles investigation,” J. Magn. Magn. Mater., vol. 433, pp. 53–58, 2017, doi: 10.1016/j.jmmm.2017.02.054.
[25] H. Zhou, L. Wu, Y. Gao, and T. Ma, “Journal of Photochemistry and Photobiology A : Chemistry Dye-sensitized solar cells using 20 natural dyes as sensitizers,” "Journal Photochem. Photobiol. A Chem., vol. 219, no. 2–3, pp. 188–194, 2011, doi: 10.1016/j.jphotochem.2011.02.008.
[26] M. R. Narayan, “Review: Dye sensitized solar cells based on natural photosensitizers,” Renew. Sustain. Energy Rev., vol. 16, no. 1, pp. 208–215, 2012, doi: 10.1016/j.rser.2011.07.148.
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