Features of spray-made lithium-doped zinc sulphide thin films
DOI:
https://doi.org/10.20221/jnmsr.v2i1.10Keywords:
Spray-made, Lithium, hexagonal, nanorod-like, zinc sulphideAbstract
The work centered on the features of spray-made Lithium-doped Zinc sulphide (ZnS) thin films. Lithium-doped and undoped ZnS films with 1%, 3% and 5% Lithium concentrations were made. The features of the films were analyzed using x-ray diffraction (XRD), UV-Visible spectroscopy, scanning electron microscopy (SEM), Fourier transform infrared (FTIR), Raman spectrometry, contact angle meter and Photoluminescence (PL) spectroscopy processes. The XRD analysis established the formation of a hexagonal phase for the samples. SEM showed nanodot-like and nanorod-like nanoparticles. The size of the particles was between 3.707 and 4.614 nm. FTIR exhibited the C=O stretching mode. The energy gap (Eg) ranged from 3.54 to 3.91 eV while the absorption coefficient is between 3.05 x 103 and 6.53 x 103 cm-1 at 3.0 eV. PL exhibited narrow band edge emission peak at 357 nm. A hydrophilic surface feature was identified. The films find application in optoelectronics and solar cells.
References
Edited by K. Kalyanasundaram (2010), Dye-Sensitive Solar Cells, 1st Ed., EPFL Press, Lausanne, Switzerland, p. 83.
Salim OudahMezan, Abdullah Hasan Jabbar, MaythamQabelHamzah, AlaaNihadTuama, NabeelNaeem Hasan and MohdArifAgam (2018), Synthesis and Characterization of Zinc Sulphide (ZnS) Thin Film Nanoparticle for Optical Properties, Journal of Global Pharma Technology, 10(07) pp. 369-373.
Chelvanathan P.,YusoffY.F.,Haque M.,AkhtaruzzamanAlamM. M.,Alothman Z.A.,Rashid,M.J.,SopianK., AminN. (2015), Growth and Characterization of RF-Sputtered ZnS Thin Film Deposited at Various Substrate Temperatures for Photovoltaic Application, Applied Surface Science, 334, pp.138–144.
P. O. Offor, B. A. Okorie, F. I. Ezema, V. S. Aigbodion, C. C. Daniel-Mkpume and A. D. Omah (2015): Synthesis and Characterization of Nanocrystalline Zinc Sulphide Thin Films by Chemical Spray Pyrolysis, Journal of Alloys and Compounds, 650, pp. 381 – 385.
Offor P. O., Okorie B. A., Lokhande C. D., Patil P. S., Ezema F. I., Omah A. D., Aigbodion V. S., Ezekoye B. A. and Ezema I. C. (2018): The Properties of Spray-Deposited Zinc Sulphide Thin Films using Trisodium Citrate Complexant, International Journal of Advanced Manufacturing Technology, 95, pp. 1849–1857 http://doi.org/10.1007/s00170-017-1326-6
AbdelhakJrad, WafaNaffouti, Tarek Ben Nasr and NajouaTurki-Kamoun (2016), Comprehensive Optical Studies on Ga-Doped ZnS Thin Films Synthesized by Chemical Bath Deposition, Journal of Luminescence, http://dx.doi.org/10.1016/j.jlumin.2016.01.016
Reza Sahraein and Soraya Darafarin (2014), Preparation of Nanocrystalline Ni Doped ZnS Thin Flms by Ammonia-Free Chemical Bath Deposition Method and Optical Properties, Journal of Luminescence, 149, pp. 170–175.
Dongyeon Son, Dae-Ryong Jung, Jongmin Kim, Taeho Moon, Chunjoong Kim, and Byungwoo Park (2007), Synthesis and Photoluminescence of Mn-Doped Zinc Sulfide Nanoparticles, Appl. Phys. Lett. 90, pp. 101910-1 - 101910-3, http://dx.doi.org/10.1063/1.2711709
Mahdi H. Suhail, OmedGh. Abdullah, Raoof A. Ahmed and Shujahadeen B. Aziz (2018), Photovoltaic Properties of Doped Zinc Sulfide/n-Si Heterojunction Thin Films, Int. J. Electrochem. Sci., 13, pp. 1472 – 1483, doi: 10.20964/2018.02.50
Özlem Işildak Ceviz, Yahya Özdemir, Metin Bedir and Mustafa Öztaş (2013), Effect of the Substrate Temperature on the Characterization of Spray-Deposited ZnS:B Films Developed in Science Parks, Journal of Optoelectronics and Biomedical Materials, Vol. 5 Issue 3, July - September 2013 p. 51 – 55.
Mahdi Hasan Suhail and Raoof Ali Ahmed, (2014), Structural, optical and electrical properties of Lead doped zinc sulfide thin films prepared by chemical spray pyrolysis technique, International Journal of Information Technology (IIJIT),Vol. 2, Issue 9, pp. 11 – 17.
Inass Abdulah Zgair, Asmahan Asaad Muhmood, Adel. H. and Omran Alkhayatt (2018), Influence of Ag Dopant Content on Structural and Optical Energy Gap of Zns Thin Films Deposited by Spray Pyrolysis Technique, Transylvanian Review: Vol. XXVI, No. 29, pp. 7809-78015.
Offor P. O., Whyte G. M., Ezekoye V. A., Omah A. D., Ude S. N., Ocheri C., Ezukwoke N., Ezema I. C., Madiba I. G., Okorie B. A., Maaza M., Ezema F. I. (2019), Structural, Morphological and Optical Properties of Spray-Formed Silver-Doped Zinc Sulphide Thin Films, Optik - International Journal for Light and Electron Optics, 185, pp. 519–528, https://doi.org/10.1016/j.ijleo.2019.03.063
Mohamed Salah, Samir Azizi, Abdelwaheb Boukhachem, Chokri Khaldi, Mosbah Amlouk and Jilani Lamloumi (2019), Effects of Lithium Doping on: Microstructure, Morphology, Nanomechanical Properties and Corrosion Behaviour of ZnO Thin Films Grown by Spray Pyrolysis Technique, Journal of Materials Science: Materials in Electronics, Journal of Materials Science: Materials in Electronics, Vol. 30, Iss. 2, pp 1767–1785, https://doi.org/10.1007/s10854-018-0449-3
Mohamed Salah, Samir Azizi1, Abdelwaheb Boukhachem, Chokri Khaldi, Mosbah Amlouk, and Jilani Lamloumi (2017), Structural, Morphological, Optical and Photodetector Properties of Sprayed Li-Doped ZnO Thin Films, J. Mater. Sci., DOI 10.1007/s10853-017-1218-z
Sayanee Majumdar and P. Banerji (2009), Effect of Li Incorporation on the Structural and Optical Properties of ZnO, Superlattices and Microstructures, 45, pp. 583–589, doi:10.1016/j.spmi.2009.03.006
Trajic,´ J., Kostic,´ R., Romcˇevic,´ N., Romcˇevic,´ M., Mitric,´ M., Lazovic,´ V., Balaz,ˇ P., Stojanovic, D. (2015): Raman spectroscopy of ZnS quantum dots, Journal of Alloys and Compounds 637, pp. 401–406.
Kim, S-Y., Hwang, C-S., (2010), Syntheses and Optical Characterizations of ZnS:Mn Nanocrystals Capped by Polyethylene Oxide Molecules of Varying Molecular Weights, Bull. Korean Chem. Soc. Vol. 31, No. 12, pp. 3834 – 3837.
Yung-Tang, N. and In-Gann, C. (2006), Raman Scattering and Electroluminescence of ZnS:Cu,Cl Phosphor Powder, Applied Physics Letters 89, pp. 261906-1 - 261906-3.
Cheng, Y. C., Jin, C. Q., Gao, 1 F., Wu, X. L., Zhong, W., Li, S. H. and Chu, P.K. (2009): Raman scattering study of zinc blende and wurtzite ZnS, Journal of Applied Physics 106, pp. 123505-1 - 123505-5.
Díaz-Reyes, J., Castillo-Ojeda, R., Martínez-Juárez, J., Zaca-Moran, O., Flores-Mena, J. E. and Galván-Arellano, M. (2014),Growth and Characterization of Zns Nanofilms Grown by Rf Magnetron Sputtering on GaAs, International Journal of Circuits, Systems and Signal Processing, 8, pp. 15 – 21.
G¨ode, F. (2011): Annealing Temperature Effect on the Structural, Optical and Electrical Properties of ZnS Thin Films, Physica B 406, pp. 1653–1659.
Kim, J.E., Hwang, C-S., and Yoon, S. (2008), Synthesis and Surface Characterization by Raman Spectroscopy of Water-Dispersible ZnS:Mn Nanocrystals Capped with Mercaptoacetic Acid, Bull. Korean Chem. Soc. 2008, Vol. 29, No. 6, pp. 1247 – 1249.
Rashi, B., Prabin, K.B., Sunandan, B. (2016), Heavy-Metal Ion Sensor Using Chitosan Capped Zns Quantum Dots, Sensors and Actuators, B, 226, pp. 534–539.
Nagamani, K., Revathi, N., Prathap, P., Lingappa, Y., Reddy, K.T.R. (2012), Al-Doped ZnS Layers Synthesized by Solution Growth Method, Current Applied Physics 12, pp. 380-384.
Nagamani, K., Prathap, P., Lingappa, Y., Miles, R. W. and Reddy, K.T. R., (2012): Properties of Al-doped ZnS Films Grown by Chemical Bath Deposition, Physics Procedia, 25, pp. 137 – 142.
Huang, W. H., Chan, S.W., Lee, Y.C. (2015): Optical Properties of Zinc Sulphide Thin Movies Prepared by Spray Pyrolysis, Fabreries Journal, Volume 4, No.2, pp. 35-40.
Ummartyotin, S., Bunnak, N., Juntaro, J., Sain, M. and Manuspiya, H. (2012), Hybrid Organic–Inorganic of ZnS Embedded Pvp Nanocomposite Film for Photoluminescent Application, C. R. Physique 13, pp. 994–1000.
P. E. Agbo, P. A. Nwofe and L. O. Odo (2017), Analysis on Energy Band Gap of Zinc Sulphide (Zns) Thin Films Grown by Solution Growth Technique, Chalcogenide Letters, Vol. 14, No. 8, pp. 357 - 363
P. O. Offor, Assumpta C. Nwanya, A. D. Omah, C. C. Daniel-Mkpume, Malik Maaza, B. A. Okorie, Fabian I. Ezema (2017), Chemical Spray Pyrolysis Deposition of Zinc Sulphide Thin Films using Ethylenediaminetetraacetic Acid Disodium Salt Complexant, Journal of Solid State Electrochemistry, 21:2687–2697, DOI 10.1007/s10008-017-3668-2.
Heine, J.R., Rodriguez-Viejo, J., Bawendi, M.G. and Jensen, K.F. (1998): Synthesis of CdSe Quantum – Dot – ZnS Matrix Thin Films Via Electrospray Organometallic Chemical Vapour Deposition, Journal of Crystal Growth, 195, pp. 564 – 568.
Downloads
Published
How to Cite
License
Copyright (c) 2023 Journal of Nano and Materials Science Research
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.